Pressure-Induced Phase Transition of Nanocrystalline Zinc Sulfide

PAN Yue-Wu; QU Sheng-Chun; CUI Qi-Liang; ZHANG Wei-Wei; LIU Xi-Zhe; LIU Jing; LIU Bing-Bing; GAO Chun-Xiao; ZOU Guang-Tian

Chinese Physics C> 2001, Vol. 25> Issue(S1) : 58-61

Pressure-Induced Phase Transition of Nanocrystalline Zinc Sulfide

National Laboratory for Superhard Materials,Jilin University,Changchun 130023,China2 Institute of Semiconductors,CAS,Beijing 100080,China3 Institute of High Energy Physics,CAS,Beijing 100039,China

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Abstract：
In situ energy dispersive X-ray diffraction measurements on nanocrystalline zinc sulfide have been performed by using diamond anvil cell with synchrotron radiation.There is a phase transition which the ultimate structure is rocksalt when the pressure is up to 16.0GPa.Comparing the structure of body materials,the pressure of the phase transition of nano zinc sulfide is high.We fit the Birch-Murnaghan equation of state and obtained its ambient pressure bulk modulus and its pressure derivative.The bulk modulus of nanocrystalline zinc sulfide is higher than that of body materials,it indicate that the rigidity of nanocrystalline zinc sulfide is high.

References

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PAN Yue-Wu, QU Sheng-Chun, CUI Qi-Liang, ZHANG Wei-Wei, LIU Xi-Zhe, LIU Jing, LIU Bing-Bing, GAO Chun-Xiao and ZOU Guang-Tian. Pressure-Induced Phase Transition of Nanocrystalline Zinc Sulfide[J]. Chinese Physics C, 2001, 25(S1): 58-61.

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Received: 1900-01-01
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通讯作者: 陈斌, [email protected]

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沈阳化工大学材料科学与工程学院沈阳 110142

Pressure-Induced Phase Transition of Nanocrystalline Zinc Sulfide

Corresponding author: PAN Yue-Wu,

National Laboratory for Superhard Materials,Jilin University,Changchun 130023,China2 Institute of Semiconductors,CAS,Beijing 100080,China3 Institute of High Energy Physics,CAS,Beijing 100039,China

Received Date: 1900-01-01

Accepted Date: 1900-01-01

Available Online: 2001-06-22

Abstract: In situ energy dispersive X-ray diffraction measurements on nanocrystalline zinc sulfide have been performed by using diamond anvil cell with synchrotron radiation.There is a phase transition which the ultimate structure is rocksalt when the pressure is up to 16.0GPa.Comparing the structure of body materials,the pressure of the phase transition of nano zinc sulfide is high.We fit the Birch-Murnaghan equation of state and obtained its ambient pressure bulk modulus and its pressure derivative.The bulk modulus of nanocrystalline zinc sulfide is higher than that of body materials,it indicate that the rigidity of nanocrystalline zinc sulfide is high.

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Pressure-Induced Phase Transition of Nanocrystalline Zinc Sulfide

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通讯作者: 陈斌, [email protected]

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